If you're starting out, these high value coupons are q's you want to SAVE! Don't run out and use them right away! Usually a release of a high value q means a sale is coming soon. When you use a coupon with a sale you get the best deal. Think of it this way- You can always buy the item full-priced with the coupon the day before the q expires. But if you wait for a sale, you can get super-cheap, free, or make money off it!
$1/1 Honey Nut Cheerios and free sample HERE
$.55/1 Snapple drink HERE (great for triples)
$1/2 Kraft Naturals Cheese HERE (Firefox) or HERE (Internet Explorer)